Archive for the ‘Notable Chemists’ Category

Some Fantastic Christmas Presents

Wednesday, January 1st, 2014

Bethany Halford and the crew at C&EN‘s Newscripts blog run an annual holiday gift guide with some cool gift ideas for chemists, but sometimes it’s more exciting to be surprised by the creativity of your family.

I got a few great chemistry presents for Christmas. The first was a Periodic Table of Magnets that I’ll put on my office door. Next, from one of my new brothers-in-law, I received a fail button in the colors of SLU that plays the sad trombone sound. I’m not sure if all of my students will appreciate this gift, so maybe I’ll keep it in an inconspicuous location. My orgo lab instructor at NYU used to have a bullseye taped to his wall captioned “hit head here”. He would point to it when students realized a silly mistake they made on a exam. I thought the sign was hilarious, but some of my classmates thought it was obnoxious.

From my other new brother-in-law, I received a copy of “How to Live Longer and Feel Better” signed by Linus Pauling. Very, very cool. Apparently, signed chemistry texts by Pauling command a much higher price tag, but I would much rather have something signed relating to Pauling’s medical quackery than chemical bonding or crystallography.

Finally, from my lovely fiancée wife, I received this:

stuffed_animal_chembark_ed

That, my friends, is total victory: a stuffed animal version of ChemBark’s mascot, Ed the Dog. I am a very lucky boy.

That’s it for the chemistry presents, but I got a bunch of other great gifts and had a wonderful wedding three days later (that will be the subject of another post). I hope everyone had as good a holiday break as I did, and best wishes for a happy and productive 2014!

How JACS Treated the Anonymous Tip of the Rodriguez–Marks Paper

Monday, November 11th, 2013

ChemBark InvestigatesBy the time the chemist who noticed the suspicious data published in the Rodriguez–Marks paper had contacted ChemBark, the chemist had already anonymously notified the Journal of the American Chemical Society with the concerns. A member of the staff at the journal responded to this initial message with the following:

To Whom It May Concern:

Thank you for your message regarding J. Am. Chem. Soc. 2009, 131 (16), pp 5902–5919. Indeed JACS takes ethics quite seriously. We would be pleased to investigate your concerns. Before proceeding, however, we ask that you reveal your identity.

Sincerely,
(REDACTED)

The implication of the official response from the journal was troubling. It implied that for the investigation to proceed, the whistleblower would need to reveal his/her identity.

Surely a journal that grants anonymity to referees would appreciate why a reader who was calling attention to possible misconduct by a well-known, powerful chemist would want to remain anonymous. Furthermore, JACS is a member of the Committee on Publication Ethics (COPE), and the source reports he reminded the journal that “COPE supports a whistleblower’s right to remain anonymous”. Beyond COPE, Ivan Oransky (co-editor of the blog Retraction Watch) has also summarized why editors shouldn’t ignore anonymous tips.

To its credit, the journal responded favorably to the source’s gentle reminder about COPE’s policy, and the investigation was allowed to proceed.

After the paper in question was retracted, ChemBark asked JACS Editor-in-Chief Peter Stang by e-mail:

When the source initially contacted the journal in August with these concerns, the journal office responded to him/her “We would be pleased to investigate your concerns. Before proceeding, however, we ask that you reveal your identity.”

As you know, the source refused to identify himself/herself and defended his/her right to anonymity in the process. While the journal eventually relented and proceeded with the review, the initial implication was that the source would need to identify himself/herself for an investigation to proceed. Was the request and wording of the initial response from the journal “standard procedure”? Is the journal worried that such a response could have a chilling effect on the identification of suspicious or irreproducible data? Why would the identity of the source matter if the concerns are reasonable?

Dr. Stang’s response included the paragraph:

I will say, however that the request for the individual to identify themselves was unnecessary. The  identity of the “whistleblower” was immaterial to the issues raised and did not  prevent JACS from considering the allegation and taking action. All ACS  Journals take all cases of alleged research improprieties very seriously and have established procedures for reviewing and taking appropriate actions, where warranted, to preserve the integrity of the scientific record. Institutions and funding agencies  also have established departments, policies and procedures for handling  allegations of data fabrication by researchers. Upholding the scientific record requires the vigilance of all participants in the research community.

All credible reports of suspicious data should be thoughtfully considered by the corresponding journal, whether reported anonymously or not. Journals should be grateful to anyone who attempts to correct the scientific record and understanding of why a tipster might want to remain anonymous. While JACS‘s initial response was troubling and “unnecessary”, it would appear as though the editors have taken steps to correct how they handle anonymous tips.

That is an encouraging outcome.

Suspicious Data in a JACS Paper from 2009

Thursday, November 7th, 2013

Covers of JACSOn Tuesday, the Journal of the American Chemical Society published a retraction notice for a paper titled “Bimetallic Effects for Enhanced Polar Comonomer Enchainment Selectivity in Catalytic Ethylene Polymerization” by Brandon A. Rodriguez, Massimiliano Delferro, and Tobin J. Marks (J. Am. Chem. Soc. 2009, 131, 5902−5919).

The retraction notice reads:

The authors have been unable to reproduce the synthesis and spectroscopic characterization of the ethylene/acrylate copolymer described in this article. Accordingly, the authors are retracting this publication due to concerns over the validity of the aforementioned data. The authors regret any confusion that may have been created by publication of this work.

A casual reader might encounter this notice and think this is exactly how the system should work: a scientist told of a problem with his published procedure went back, attempted to repeat the work, found he couldn’t, and published a notice to inform the community.

But a closer inspection reveals that there is more to this story that the retraction notice would indicate.

ChemBark was alerted to problems with this paper in August by an astute chemist who wishes to remain anonymous. One day earlier, the source had contacted Peter Stang, the editor-in-chief of JACS, to alert the journal to abnormalities with data in the paper. ChemBark respected the wishes of the source and allowed a traditional editorial review of the paper to be completed before reporting the matter on the blog. With the publication of the retraction notice yesterday, the authors have publicized that their work is problematic. It would appear that an initial review of the paper is complete.

The authors’ wording of the retraction does not indicate specifically what was wrong with the paper, but a brief inspection of the data (including those in the Supporting Information) reveals the following abnormalities:

Figure 3: The baselines of these spectra are peculiar in that they are thick but very straight. The thicknesses and shapes of the peaks are also peculiar. Some of the tall peaks lack the wide bases you would expect of them. Finally, some of the peaks appear to have a different background (i.e., noise) and line thickness (as if they originated from a different source).

marks_retraction_figure_3

Figure 6: The baselines (i.e., noise) of the two NMR spectra appear to be identical. The peaks look irregular—like solid lines.

Figure 7: Again, some of the peaks have lines that are much thicker than the rest of the spectrum. They look unnatural.

Figure S19 (in the SI): The NMR spectra taken at various temperatures have identical noise in their baselines, which would be very, very unusual. The peaks of interest appear irregular and have different line shapes.

marks_retraction_figure_s19

Figure S21: The background of the peaks appears different from the background of the rest of the spectrum, as if the peaks were cut-and-pasted into the spectrum.

Figure S22: Same as above. The spectrum in Figure S21 and the bottom spectrum of Figure S22 appear to have the same baseline noise even though these spectra are reported to be of two entirely different compounds.

marks_retraction_figure_s22

That’s not everything that looks peculiar, but do not simply take my word for it. Go to the paper, have a look, and judge for yourself (paper, SI). ChemBark does not know why these data look the way they do, but they do look unnatural.

On Tuesday, ChemBark contacted Professors Tobin Marks (the corresponding author on the retracted paper) and Peter Stang (the Editor-in-Chief of JACS) by e-mail for comment.

A response was received on Wednesday from Alan K. Cubbage, the chief communications officer for Northwestern University. In the interest of fairness, we are reporting this e-mail its entirety:

Mr. Bracher, your inquiry to a Northwestern University professor, Tobin Marks, was referred to me, as I am the chief communications officer for Northwestern.

As you note in your email, two Northwestern University faculty members and a former Ph.D. student have retracted a publication that appeared several years ago in the Journal of the American Chemical Society. The authors are Brandon A. Rodriguez, who received a Ph.D. from Northwestern in 2009, Tobin Marks, a professor of chemistry, and Massimiliano Delferro, a research assistant professor of chemistry. The article was retracted because the authors were unable to reproduce a portion of the data described in the article.

Northwestern University has established processes and procedures for reviewing issues relating to research integrity.  If concerns were to be raised regarding the data that was the subject of the retraction, the University would use those procedures in its review.  Part of those procedures, which follow the steps mandated by the federal government, is that any review remains confidential.

Thank you for your interest in Northwestern.

Best wishes,

Alan Cubbage

ChemBark also received an e-mail response from Peter J. Stang, the Editor-in-Chief of JACS. In addition to asking about the possibility of fabrication and the specific concerns listed above, we asked for his thoughts on Paul Weiss’s recent editorial in ACS Nano. Dr. Stang’s message is also copied below in its entirety, with the exception of one paragraph (that will be communicated in the next post on the blog, a follow-up to this story):

Dear Dr. Bracher:

Thank you for your communication regarding  Bimetallic Effects for Enhanced Polar Comonomer Enchainment Selectivity in Catalytic Ethylene Polymerization   authored by Brandon A. Rodriguez, Massimiliano Delferro, and Tobin J. Marks [http://dx.doi.org/10.1021/ja900257k] that has been retracted {10.1021/ja409590r] from the Journal of the American Chemical Society (JACS).

As you know, concerns with this paper were brought to my attention in late August by an anonymous source.  Apparently this source also communicated the same concerns to you.  I am disappointed that you felt obligated to  not communicate these concerns  to JACS directly  at that time and deferred to your source to do so. Please know that JACS takes all allegations regarding the validity of  data reported in published articles very seriously.

These concerns were shared with the author and a  thorough editorial review of the article and accompanying information was conducted by JACS. The authors have retracted the article – it would not be proper to speculate on some of the questions you have posed.

(Omitted paragraph — to be discussed in next post)

ACS and its Editors adhere to the principle that the observance and practice of high ethical standards is vital to the entire scientific enterprise.  Toward that end, guidelines for a course of conduct by those engaged in the publication of chemical research, specifically, editors, authors, and manuscript reviewers are set forth in ACS Ethical Guidelines to Publication of Chemical Research -http://pubs.acs.org/userimages/ContentEditor/1218054468605/ethics.pdf.

ACS Publications  is a member of the Committee on Publication Ethics (COPE). ACS Editors adhere to  a process established by COPE to review suspicious/fabricated data -http://publicationethics.org/files/u7140/Flowchart%20Fabricated%20B%20revised.pdf

With regard to the editorial in ACS Nano, I believe that it is well-reasoned and articulated. Public speculation and  finger-pointing before all of the facts are gathered, assessed and decided upon is, in my opinion, counterproductive.  A confidential rigorous review of allegations based on the COPE  prescribed process is the best means to determine an appropriate action in response to those allegations.  As you know, outcomes of these reviews may very well have a lasting impact on the researcher(s) involved and we need to let the facts dictate those outcomes.

Thank you for advising that ChemBark will post a story on the retractionhttp://pubs.acs.org/doi/abs/10.1021/ja409590r. I offer my assistance in reviewing a draft and through cc have alerted  Dr. Tobin, the corresponding author.

Peter J. Stang

 

ChemBark could not locate an e-mail address for Dr. Brandon Rodriguez, the first author on the paper, but did send him a message seeking comment through Facebook. We received no reply. We will publish any comments from Dr. Rodriguez as soon as possible after they are received, and we note that he (and everyone) is welcome to post comments in the discussion thread below. We also note that the community owes a debt of gratitude to the chemist who brought these concerns to light in a professional and considerate manner.

So…here we have a case where a suspicious paper from a very high-profile group was allowed to go through the “traditional” private review process espoused by scientists like the editor-in-chief of ACS Nano rather than public review on a blog. ChemBark did nothing to interfere with the investigation or the actions of the editors at JACS.

Is this how the system should work?

 

Editor’s Notes: Neither Dr. Stang nor anyone at Northwestern were allowed to view an early draft of this story. The spectra used to construct the images above were taken from figures in J. Am. Chem. Soc. 2009, 131, 5902−5919 (paper, SI). The next post on ChemBark will deal with how the journal handled a specific aspect of this review.

Questionnaire Answers from Dr. Diane Schmidt, Candidate for ACS President-Elect

Thursday, October 31st, 2013

Earlier this month, ChemBark sent a questionnaire to the three current candidates for ACS President-Elect. The set of questions was similar to the set distributed last year that Tom Barton was kind enough to answer.

ChemBark is publishing each candidate’s response—complete and unedited—in dedicated posts. Dr. Chuck Kolb’s answers and Dr. Bryan Balazs answers ran in previous posts. The next candidate to respond is Dr. Diane Schmidt (whose response was delayed due to jury duty). Her answers appear below.

Don’t forget to vote in the ACS national elections!

 

Response of Dr. Diane Schmidt, Candidate for ACS President-Elect

1. What are your thoughts about the historically low voter turnout (~15%) typical of ACS national elections?

Apathy is difficult to cure. One suggestion would be to have greater publicity in C&EN (perhaps a cover article) to raise the profile and awareness of the national elections. The option to vote electronically does not appear to have had the impact of  greater participation in the national elections that was expected.

2. What is your stance regarding the fees that ACS Publications charges companies and universities to access journals?

Journal pricing is complex and is probably best understood by dealing in specifics for specific schools and companies rather than generalities.  When I get these questions, I always refer people to Pubs.  In many cases there are custom solutions that can be crafted for individual circumstances.

My view is that ACS journals offer high value and high impact at competitive pricing. The quality and the value of the trusted, peer reviewed information provided by ACS journals is a very good value vs. other publishers.

3. What is your stance on the ACS’s executive compensation packages?

Full transparency is important. Perhaps a C&EN comment on the process that is used would help get everyone on the same page as to what is actually in place and the process that is used to determine compensation.

You may remember that the Board held a town meeting on Executive Compensation after Council in Fall, 2005, and perhaps a refresher is in order via a C&EN comment. C&EN calls attention to the ACS Form 990 filing each year and tells readers how to access that document on acs.org. Here’s the link to the 990 notice on page 6 of C&EN.

http://www.cendigital.org/cendigital/20121210??pg=8&search term=990&doc id=-1&search term=990#pg8 

4. What are your thoughts on the recent ACS vs. Leadscope case? Do you believe that society records pertaining to the lawsuit—including legal fees—should be made public?

Full transparency is important.

The background as I recall is that all public reports on Leadscope in the early days were modulated by the fact that it was active litigation.  The events relating to the litigation go back to 1998. For a long time, virtually nothing happened, then there was the trial.

For nearly a year after the settlement in 2012, an extensive Q&A was advertised on the front page of the ACS website. It can still be found at:

http://www.acs.org/content/acs/en/about/aboutacs/acs-v-leadscope-questions-and-answers.html

One of the difficulties I think with this case is it spanned quite a number of years perhaps making it difficult to follow. My impression is there were regular updates in C&EN over the course of the legal proceedings as the case unfolded, reports in Council of the case status by the Chair of the Board, as well as updates in the Councilor Bulletin. Perhaps a summary in C&EN tying all of the bits and pieces together that were published over time as the case unfolded would be helpful with links to the publically available information. My understanding is that the Chair of the Board reports which include Leadscope are posted on the ACS website.

The most recent report on Leadscope and the financial impact on ACS was by the Chair of the Board  and was presented in Council last Spring. I believe his remarks are posted on the ACS web.

My understanding is that the proceedings of this case are in the public record. To read a summary of the case prepared by the Supreme Court of Ohio’s Office of Public Information, click here: http://www.courtnewsohio.gov/cases/2012/SCO/0918/101335.asp

5. What one specific item would you, as ACS President, make your first priority to improve the public perception of chemistry?

Outreach. Chemistry improves the lives of all. Communicating specific examples such as chemistry’s role in clean water, food safety, medicinal improvements, diagnostic techniques, etc.  that the general public experiences daily, but does not identify as chemistry. This would help make the connection between the role of chemistry and the improvements the general public experiences in daily life because of the contributions of chemists and chemistry. The ACS Landmarks Program does this to some degree. During the International Year of Chemistry, many examples of how chemistry improves life daily were posted on the ACS website. There is an opportunity to go the next step and more broadly communicate these.

6. What one specific item would you, as ACS President, make your first priority to improve the employment situation for chemists?

Ensure that all members and all chemists know of and have access to the many ACS employment tools and services already in place. Work with staff and members to further enhance, expand and improve these tools.

7. What is your favorite chemical compound with respect to color or smell?

My favorite chemical compound is caffeine, especially delivered in chocolate. It was my first total synthesis as an undergraduate.

Response to ACS Nano Editorial on Reporting Misconduct

Wednesday, October 23rd, 2013

ChemBark's Jackie Jaws, the Jaded JACS RefereeYesterday, the entire editorial board of ACS Nano published an editorial on how scientific misconduct should be reported and dealt with. The piece took square aim at chemistry blogs, and I’ve decided to publish my thoughts as an open letter to Paul Weiss, the Editor-in-Chief of the journal:

Dear Professor Weiss,

Yesterday, I read your editorial titled “Be Critical but Fair”, within which you and the other editors of ACS Nano outline an official policy that calls on those who discover suspicious data to report their findings directly to the journal (where they can be scrutinized privately) as opposed to blogs and social media (where the findings will be scrutinized in the open). It is with candid disdain that I write this (public) blog post to explain why I believe your policy is misguided, and ultimately, damaging to the institution it seeks to protect.

Before going further, I want to thank you for the job that you and the rest of the board perform as editors. You are the primary stewards of the chemical literature, and the gravity of this responsibility is immeasurable. I imagine there are times when the extra salary you receive as editors does not adequately compensate you for the hassles of the job. I have no taste for this stress, but I am glad there are scientists among us willing to step up to the plate. Thank you for your service.

It is because of the immense responsibility of your job as a steward of the chemical literature that the community has an interest in analyzing your actions and holding you accountable for them. Everyone makes mistakes—from lowly chemistry bloggers to exalted editors-in-chief of ACS journals—but the true tragedy of any mistake is when we fail to learn from it. Recently, the process of peer review at your journal failed in a most spectacular manner. Similar high-profile cases recently occurred at your sister journals (e.g., Nano Letters and Organic Letters), and these cases of suspected misconduct are slowly working their way through the process of editorial review.

One common vein to this recent rash of suspicious papers is that they were brought to light on chemistry blogs. As you may already know, I am the editor of one of these blogs, ChemBark. I read with particular interest the comments you directed at those who discuss misconduct on blogs and Twitter:

In science, we face a similar problem: the numbers of blogs, twitter messages, etc. in which individuals accuse others of academic fraud are steadily rising. Although one might think that this trend is generally beneficial for the purity of science, there are also obvious risks involved. Thus, in this Editorial, we outline some general behavior guidelines that we believe should be followed in such cases. In general, we need to respect our law, in dubio pro reo, which tells us not to condemn anyone before wrongdoing has been proven. It is easy to tweet a message like “X committed fraud and manipulated data”, but how do we know that this is, in fact, true, and that instead, it was perhaps person Y who sent the tweet who just wanted to damage an unwanted competitor? We are convinced that it is important to “clean” the scientific literature from manipulated data, incorrect statements, plagiarism, etc. However, when these issues arise, they need to be investigated with good scientific conduct. In other words, be critical but fair.

The implication of your last statement is that the coverage of scientific misconduct by ChemBark was unfair, and I take great offense to this postulate. I use this word because you have not cited a single shred of specific evidence in support of your statement. When has a chemistry blogger ever raised serious suspicions about the validity of data in a paper only to be later proven incorrect? If a researcher submitted a manuscript to ACS Nano that did not include even one specific piece of data in support of his conclusions, the journal would reject the manuscript immediately. It is a shame that the editors do not hold their own writing to a similar standard.

You said on Twitter that the journal has a policy never to cite blogs or tweets, as if this represents a valid defense of why you couldn’t provide specific facts in support of your ideas. First, your tweet was absolute rubbish. Stuart Cantrill, chief editor of Nature Chemistry, immediately pointed out you wrote a previous editorial that cited the Retraction Watch blog. Second, why on Earth would you have a blanket policy not to cite blogs or tweets? Is ACS Nano so recalcitrant to changes in the publishing industry that it feels ideas voiced online can be ignored or reapportioned in print without credit? I hope not.

The true reason that your editorial did not cite a single instance of a blogger’s leveling false accusations of scientific misconduct in chemistry is that no such instance exists. To imply otherwise is dishonest sophistry that does not befit the editors of a major chemistry journal. In the very rare instances where commenters make weak accusations in the discussion thread of a blog post, the comments are ignored or ridiculed. Despite the fact that the majority of popular chemistry blogs serve as places for civil and thoughtful analysis, your editorial treats blogs as shady underground operations where anonymous bloggers are free to wreak havoc on innocent scientists. Again, I challenge you to find one anonymous chemistry blogger who has broken a story of possible misconduct. I use my real name on ChemBark, and Mitch Garcia blogs under his real name at Chemistry-Blog. Your editorial could have easily cited our work in reporting suspicious papers, but of course, doing so would not have fed into your desired narrative.

Returning to your statement above, you note that “we need to respect our law, in dubio pro reo, which tells us not to condemn anyone before wrongdoing has been proven.” First off, your translation isn’t even correct. A more accurate translation is “when in doubt, favor the accused.” This tenet is why our legal system requires proof “beyond a reasonable doubt”, and the idea has nothing to do with trying cases in public versus private. The fact that you drew on our legal system—which is famous for holding trials that are televised or open to members of the public—to support your policy is ridiculous.

While bloggers who report cases of possible misconduct are indeed accountable to the law, that law is not “in dubio pro reo”. Rather, bloggers are accountable to defamation law. If any chemistry blogger were to raise baseless accusations of misconduct against a scientist, the blogger would open himself to (i) financial ruin from an adverse finding in a civil claim, and (ii) professional ruin in the court of community opinion. Bloggers need to be careful about what papers they choose to highlight regarding scientific misconduct, but this is no different from how newspapers and magazines need to be careful about how they handle their coverage of crime in everyday life. Do we want newspapers to abstain from reporting major crimes until a trial by jury has concluded? No, that’s crazy. There is a public interest served in covering these stories, and news outlets play a valuable role in gathering, distilling, and reporting this information. As both a chemistry blogger and a human being, I need to make sure that the facts I report regarding possible scientific misconduct are accurate and the opinions I voice are rooted in reason. That’s the bottom line, and I am accountable to the very intelligent readership of the blog and to our legal system (should someone have a problem with my coverage). No blogger can expect to level spurious claims of misconduct and get away with it.

Your editorial continues with a statement that peer review is “the best way to avoid potential academic fraud” and correctly notes that the system sometimes fails. When it does, you implore readers who find evidence of misconduct to report it directly to you so you can conduct an investigation in private. You note:

The difference between this formalized accusation investigation and reports in blogs or on Twitter is that, during the investigation, the authors of the article under dispute have a fair chance to explain, and the decisions are made by known experts in the field. After we have made our decision, all are welcome to comment on it in any blog, even if they have different opinions; this is their privilege. We strongly suggest that such comments be made without the cloak of anonymity, using real names and affiliations, so that direct and open discussion of the work can be understood by others.

I hope you can appreciate the irony of how you begin by extolling the virtues of (anonymous) peer review and conclude by haranguing bloggers and commenters to register their opinions “without the cloak of anonymity.” It takes a lot of gall to make those statements in the same line of thought.

Furthermore, the idea that the public should not be free to point out deficiencies of a (publicly) published paper without first receiving clearance from the editorial board of ACS Nano is preposterous. The notion is antithetical to the freedom of inquiry espoused by the academic community and the freedom of speech held sacred by American society. Unless I am mistaken, the “A” in ACS Nano stands for American. In America, it is not a “privilege” to comment publicly on a subject; it is a right.

Your assertion that commenting on papers is a “privilege” smacks of the elitist, opaque, closed-door, Old-Boys’-Club approach that many lament has become standard operating procedure in too many areas of chemistry. Many young chemists decry that success in our field is not so much about what you do, but whom you know. Blogs are helping to level the playing field by putting users on equal terms and democratizing the flow of information. In order for any self-governing and self-policing body to operate effectively, members of the community must stay informed about important issues they face. There can be nothing more important to chemistry than the integrity of our data; it is the foundation on which our knowledge is built. Private systems of dealing with misconduct do so in a darkness where—even if an investigation takes place on the level—those outside will always have their doubts. The open system afforded by blogs shines a light on problems so all can see, participate, and judge for themselves. While private peer review of papers may make sense to eliminate errors before they’ve been published, once a paper is out in the open, it should be fair game for comment. There is no point in dragging problems back inside only to leave a trail of blood and a multitude of questions behind.

I would like to think that the private system you espouse could also function efficiently, but recent history has proven otherwise. Despite the importance of maintaining the integrity of the scientific record, the chemical community has been routinely kept in the dark about cases of scientific misconduct. Journals, universities, and governments seem to share as little as possible about their investigations. Just look what happened with the Sezen–Sames retractions. The case involved a shocking rampage of deceit and was probably the worst scandal to hit organic chemistry of all-time, but it took a FOIA request from me and C&EN to release the details of the case to the community. How can chemists be expected to learn from and prevent scandals without knowing any of the specific details? It’s ridiculous! Do you pledge to release all of the specific details of your investigations that result in adverse findings against an author?

Journalism—including that provided on chemistry blogs—is one way to address this vacuum of information. The Founding Fathers of the United States protected the freedom of the press in our Bill of Rights because they knew that an informed electorate was essential to the efficient operation of our government and the prevention of tyranny. A (small) part of what I’ve tried to do with ChemBark is to shed light on cases of scientific misconduct in our field such that these cases can be discussed and analyzed by the wider chemical community. It is unfortunate that there exists a need for bloggers to invest some of their time in this effort, but experience has repeatedly shown that chemists cannot rely alone on journals, universities, and governments to keep them informed.

Regardless of how persistent you are in your attempt to intimidate the blog community into keeping silent, bloggers will continue raising these issues. The health of our science is at stake, and the importance of its protection far exceeds the cost of however you and your colleagues decide to punish us for openly analyzing important issues in our field.

In summary, I believe your editorial is unfair and completely misguided. I am dismayed that it represents not only your personal opinion, but the professional opinion of every member of your editorial board (who signed it). You all have perverted an embarrassing, spectacular failure of peer review at your journal into a condemnation of the community that exposed and prevented the proliferation of your error. Chemists should be outraged at your editorial, and I hope they see through this shameless attack on those of us who use blogs and social media to analyze articles rather than the traditional method of grumbling in solitude. In the future, I suggest your effort will be better spent listening to the constructive feedback bloggers and their readers provide rather than attacking them for conducting their analysis in a public forum. Finally, on Twitter yesterday, you mentioned a willingness to engage further in a discussion of the merits of open vs. closed review of problematic published papers. I do not hold grudges and would be happy to participate in whatever forum you deem appropriate. Please keep me informed if you remain interested in hosting such a symposium.

Yours in chemistry,
Paul

Questionnaire Answers from Dr. Bryan Balazs, Candidate for ACS President-Elect

Monday, October 21st, 2013

Earlier this month, ChemBark sent a questionnaire to the three current candidates for ACS President-Elect. The set of questions was similar to the set distributed last year that Tom Barton was kind enough to answer.

ChemBark will publish each candidate’s response—complete and unedited—in dedicated posts. Dr. Chuck Kolb’s answers ran last week. The next candidate to respond is Dr. Bryan Balazs. His answers appear below.

Don’t forget to vote in the ACS national elections!

Edit: This post has been corrected to include the correct spelling of “Balazs”. (We regret the error!)

 

Response of Dr. Bryan Balazs, Candidate for ACS President-Elect

Hi Paul,

With the excitement of the Nobel prizes now (somewhat) behind us, here are my responses to your questions posed below.  Let me know if there are any statements that need additional clarification, and thanks for the opportunity to address your readership on these important topics.

Cheers,
Bryan

PS:  If the answers are too long, I can shorten them.

 

1. What are your thoughts about the historically low voter turnout (~15%) typical of ACS national elections?

I wish this were a higher percentage, as elections are the opportunity for all members to have a voice in who will be the representative of their Society to the membership, to the public, to government, and to other countries.  The ACS is the largest scientific society in the world and with this size come challenges in effective engagement with the membership.  The candidates do have different strengths, backgrounds, and platforms, and the ACS President definitely can influence the future of the Society.  What the low turnout tells us is either: A) members do not follow the elections or care about the outcome, B) the reason they are ACS members is unlikely to be influenced very much by who the President is, or C) members do not know any of the candidates and don’t wish to participate in an election without having an informed vote.  If would like to understand the relative influence of each of these three possibilities, and if there are other reasons  Until we get this information, what can we do in the meantime to improve this?  Here are a few ideas I would like to suggest:  1. The members don’t get many opportunities to interact with the candidates and vice versa. The current election rules are very restrictive and so, we should explore ways for the candidates to reach out to members, and the ACS could provide more resources for the candidates to facilitate this; 2. To make it easier to vote, ACS should move towards a default of electronic voting rather than the current paper ballot with an option to vote online; 3. Members who vote can influence and encourage friends and colleagues to vote.  This sounds simple but can have a huge effect in the voting rates; and finally 4. We can nurture voting regularity in younger members by providing some kind of membership incentives as a result of voting.

2. What is your stance regarding the fees that ACS Publications charges companies and universities to access journals?

I have heard from many members, especially those at small colleges or companies that the journal prices are raising at an unsustainable rate for them and they wish that there were other pricing options.  This is indeed a problem not only for ACS publications but also other publications like Nature, to the point where universities are considering boycotting journal subscriptions.  Also, there has been an increase in open access journals, a trend ACS has to keep in mind. While there should be no restrictions in the spread of knowledge, unfortunately, publishing and circulation of these journals (both online and physical copies) does come with costs.  We need to explore ways to keep these costs under control, and academia, industry and the scientific societies need to have a serious dialogue on this issue.  This needs to happen because it directly affects our members.

3. What is your stance on the ACS’s executive compensation packages?

Within any organization, the pay that an employee receives should correspond to the value that this employee provides to the organization, and the ACS should be no different.  All salaries must be benchmarked against market conditions, keeping in mind that the ACS is a complex non-profit organization with over 160,000 members, about 2000 staff members, and about a billion dollars in assets.  Executive compensation packages should reflect this, and the ACS has been very transparent about this information; see https://www.acs.org/content/acs/en/about/aboutacs/financial.html (see part VII in the 2011 IRS Form 990 for info on executive compensation).

4. What are your thoughts on the recent ACS vs. Leadscope case?  Do you believe that society records pertaining to the lawsuit—including legal fees—should be made public?

I am familiar with only the basic facts of the case, such as those published by the ACS in C&EN or in the Councilor bulletins.  To be honest, I really don’t have a strong opinion in this case, but it sounds like the ACS made logical decisions as the legal process unfolded.  The ACS has said that the legal judgment against the ACS will not affect member dues or benefits, and I take their word on this.

5. What one specific item would you, as ACS President, make your first priority to improve the public perception of chemistry?

The public listens to celebrities and other people in the public spotlight, and I believe we should tap into this.  Many of these people are enthusiastic about science, so why not partner with them to help spread the message about the value of chemistry (science in general)?  I think having actor Alan Alda at the recent national meeting in Indianapolis was a superb idea, and I would do more of this.

6. What one specific item would you, as ACS President, make your first priority to improve the employment situation for chemists?

This is a complex issue, but ACS can do a better job of bridging the employers with new opportunities (employees).  My thoughts are as follows:

There is no doubt that chemists are in a competitive job market in the current challenging economic times.  In my opinion, applicants need three things to land a job: 1) they need to find out about job openings (this goes without saying), 2) they need to have the required skills for the job, and 3) they need to outshine the competition when it comes to the application and interview process.  The ACS needs stronger efforts for its members in each of these areas.  Quite frankly, the ACS does not do a very good job at identifying for its members where the jobs are and who IS hiring (item number 1).  This can be improved by coming up with a database of websites that ACS member can use to locate the jobs that they might be qualified for, including companies that are “non-traditional” employers of chemists.  With item number 2, skills, I feel that in the fast changing competition from talent around the world, we need to constantly encourage our students and work force to keep learning new skills, even while in a job.  One of the latest trends in our education system is the onset of online courses.  I will extend my efforts to explore collaborations between ACS and institutions offering such courses to benefit our members.  For item number 3, the ACS has good resources to help members polish their resume, work through the application process, etc., but surprisingly few members take advantage of these resources.  We need to find out why, and we need to improve this.  One of the areas we can improve is to offer online services for those seeking help with item number 3.

7. What is your favorite chemical compound with respect to color or smell?

I have lots of favorite chemicals and elements, but one that comes to mind is malachite green, or [C6H5C(C6H4N(CH3)2)2]Cl.  My organic chemistry professor in college, who had a rather mischievous sense of humor, had the students synthesize malachite green in the organic lab around St. Patrick’s Day.  Malachite green is a very intense dye, and the end result of all these students synthesizing this compound was that the hallways of the chemistry building turned green, and students’ furniture, clothes, bedsheets, and so forth had a green tinge.  Pretty amusing, unless of course you had a car with white leather seats…!